Applied electrochemistry, articles of Moscow schools and individuals

This page collects representative contributions from various Moscow institutions related to galvanics, corrosion protection, and applied electrolysis. Note that non-academic Institutes from Moscow had systematic intersections with the Institute of Physical Chemistry (see corresponding articles are at a separate page, e.g. N.A. Izgaryshev’s articles affiliated with this Institute). M.Ya. Fioshin had a lot of joint works with Karpov Inst, and also with L.I. Krishtalik and with B.N. Kabanov.

Drozdov N.S. Electrochemical oxidation of the three-valent chromium into chromic acid // Zhurnal Obshchei Khimii. 1933. V. 3. P. 345-350, in Russian. Supposedly, the author is Nikolay Sergeyevich Drozdov (1902-1963). Indicated affiliation ‘Tropical Institute’ is known as one of the interediate names of the Institute of Tropical Medicine, which now belongs to the 1st Moscow Medical University.

Stepanov D., Marshak F., Belyakova E. Electrolytic plating of iron-nickel alloy // Zhurnal Obshchei Khimii. 1935. V. 5. P. 30-33, in Russian.

Stepanov D., Marshak F. Oxidation of solutions of stannous sulfate // Zhurnal Obshchei Khimii. 1935. V. 5. P. 289-293, in Russian. Related to stability of electrolytes for galvanic tinning.

Izgaryshev N.A., Maiorova E.Ya. On the electrode processes of deposition and dissolution of metals depending on the nature of ions and concentration // Zhurnal Obshchei Khimii. 1936. V. 6. P. 1208-1229, in Russian.

Izgaryshev N.A., Grigoriev N.K. Electrocatalytic release of lead and zinc from their sulfides // Zhurnal Obshchei Khimii. 1936. V. 6. P. 1676-1685, in Russian.

Sokolov P.I. Concentrational polarization in the course of water electrolysis // Zhurnal Obshchei Khimii. 1936. V. 6. P. 1721-1728, in Russian.

Kryukov P.A., Kryukov A.A. Metallized glass electrode // Zavodskaya Laboratoriya. 1937. V. 6. P. 619-621, in Russian. The work is affiliated with Soil Science Institute, where Petr Alekseyevich Kryukov (1906-1991) worked before WWII (finally moved to Novosibirsk, his 1964 DSc thesis addresses soil suspensions). Presumably, the second author is his father Alexey Aleksandrovich (1872-1949), who worked as spa physician during this period, and was very active with research of mineral water. Metallization of glass allows to use very thin glass avoiding high resistance. The next communication of P.A. Kryukov on calomel electrode: Zavodskaya Laboratoriya. 1937. V. 6. P. 1495, in Russian

Vainshtein G.M. Determination of the specific conductivity of river water from the internal resistance of galvanic cell // Zavodskaya Laboratoriya. 1937. V. 6. P. 1471-1474, in Russian. Affiliated with Rublevo pumping station (pre-revolutionary waterworks, which played major role in Moscow water supply). We can assume that the author is Georgyi Mikhailovich Vainshtein, known later for his hydrotechnical publications. A bridge with river water is located between two half-cells of Daniel battery.

Zvyagintsev O.E., Amosova L.K., Vorob’yeva A.V., Khananov N.M. Experience of electrolytic platinization and palladization of copper // Zhurnal Prikladnoi Khimii. 1937. V. 10. P. 1969-1979, in Russian, Abstract in French (P. 1978-1979). Orest Evganievich Zvyagintsev (1894-1967) was an expert in technologies of noble metals, who worked in industry (Ural), and later in Moscow, mostly in the Istitute of General and Inorganic Chemistry.

Mel’nikov N.N. Electrochemical synthesis of organic comounds // Uspekhi Khimii. 1937. V. 6. P. 4-41, in Russian. Review with 228 Refs, edited by S.I. Sklyarenko. We can assume that the author is Nikolay Nikolayevich Mel’nikov (1980-2000), who started in military-oriented chemistry, and later mostly worked on pesticides chemistry. The editor is Sergey Ivanovich Sklyarenko (1897-1862), originating from Izgaryshev’s school. He worked in the military-chemical academy and teached in a number of technical universities. His research covered galvanics, electrometallurgy, and sometims also inorganic chemistry (example from Zhurnal Obshchei Khimii. 1953. V. 23. P. 1121-1126).

Pshenitsyn P.A., Lavrovich O.S. New electrolyzer for electrolytic decomposition of alkaline <alkali?> sallts // Zavodskaya Laboratoriya. 1938. V. 7. P. 622-623, in Russian. Affiliated with the Lab of construction materials to built the Palace of Soviets <Дворец Советов>. This building was, in the end, not implemented political project. The first author worked on concrete-related topics later.

Lyapuntsova T.G., Barashenkova A.I. Anodic oxidative <treatment> (blackening) of copper and brass // Zhurnal Prikladnoi Khimii. 1939. V. 12. P. 30-33, in Russian, abstract in French (P. 33).

Kochergin S.M. On the theory and practice of nickel galvanoplastics // Zhurnal Prikladnoi Khimii. 1939. V. 12. P. 44-45, in Russian. The author is mostly associated with Kazan, but in mid 1930s he worked at the factory in Noginsk near Moscow.

Biryukov N.D., Makarieva S.P. The effect of temperature on chromium deposition from chromic acid solutions // Zhurnal Prikladnoi Khimii. 1939. V. 12. P. 818-825, in Russian, abstract in French (P. 825).

Biryukov N.D., Melikhov G.I. The effect of sulfuric acid on oxidation-reduction processes in the course of chromium plating // Zhurnal Prikladnoi Khimii. 1939. V. 12. P. 855-861, in Russian, abstract in French (P. 861).

Agladze R.I. On the complex ions in solutions containing the salts of manganese and ammonium // Zhurnal Obshchei Khimii. 1940. V. 10. P. 340-346, in Russian. The help of P.M. Lukyanov, supervisor of Agladze’s PhD thesis in Moscow Chemical-Technological Institute, is acknowledged. This, the next (1941) and also delayed 1943 article are the parts of Agladze’s PhD thesis (about 1938). His PhD study formed a basis for developlemt of manganese industry in Georgia.

Shpigel’ N.A. Current dissipation in solutions // Zhurnal Obshchei Khimii. 1940. V. 10. P. 2077-2086, in Russian.

Biryukov N.G., Veselovskaya I.E. The effect of current density on chromium deposition // Zhurnal Prikladnoi Khimii. 1940. V. 13. P. 1315-1321, in Russian, abstract in French (P. 1320-1321).

Morokhov M.I., Stepanov D.V., Moroko S. Electrolytic nickel deposition in presence of arsenic // Zhurnal Prikladnoi Khimii. 1940. V. 13. P. 1322-1325, in Russian, abstract in French (P. 1325). This is the latest article we found with indication of the lab of technical electrochemistry of the Karpov Institute. This does not mean that D.V. Stepanov still worked in the Institute, as some publications could be strongly delayed.

Stepanov D.V., Lyashchenko I.P. Hard <and> bright nickel plating // Zhurnal Prikladnoi Khimii. 1941. V. 14. P. 281-290, in Russian, abstract in German (P. 290).

Agladze R.I., Fedorova N.S. Electrolytic preparation of manganese amalgam // Zhurnal Prikladnoi Khimii. 1941. V. 14. P. 305-316, in Russian, abstract in French (P. 316).

Levin L.E. A new type of calomel electrode // Zavodskaya Laboratoriya. 1941. V. 10. P. 328, in Russian. Institute of Organic Intermediates and Dyes, Moscow; the author patented a number of solutions for automatic pH measuremets in aniline industry. Design of the electrode is rather similar to modern commercial reference electrodes.

Agladze R.I. Cathodic deposition of metallic manganese from aqueous solutions // Zhurnal Prikladnoi Khimii. 1943. V. 16. P. 337-347, in Russian. Participation of M.M. Khomyakova and V.N. Modestova is mentioned. The article was submitted in 1940.

Krasil’shikov A.I. Action of mineral acids on iron // Zhurnal Obshchei Khimii. 1944. V. 14. P. 261-269, in Russian, Abstract in English (P. 269).

Lainer V.I. Electrochemical polishing of metals. I. Electrochemical polishing of nickel // Zhurnal Prikladnoi Khimii. 1945. V. 18. P. 236-246, in Russian.

Izgaryshev N.A., Aryamova I.I. The study of cathodic process in the course of electroreduction of oxalic acid // Zhurnal Obshchei Khimii. 1948. V. 18. P. 337-344, in Russian.

Mikhailov V.V. Electrocrystallization of metals // Uspekhi Khimii. 1949. V. 18. P. 724-736, in Russian. Vladimir Vasilievich Mikhailov defended his PhD thesis on Cu plating in the Moscow Chemical-Technological Institute (1950). An interesting aspect of this article is presentation of Glazunov’ works, in essentially different context than in systematic modern article.

Chizhikov D.M., Ustinskyi B.Z. Electrolysis of nickel sulfate in electrolyser with non-filtering diaphragm // Zhurnal Prikladnoi Khimii. 1949. V. 22. P. 1306-1309, in Russian.

Modestova V.N. The effect of anions on the kinetics of cathodic oxygen reduction // Zhurnal Fizicheskoi Khimii. 1951. V. 25. P. 1138-1139, in Russian. This is a part of 1953 PhD thesis of Vera Nikolaevna Modestova completed in the Moscow Chemical-Technological Inst (later she worked in corrosion Dept of the Inst of Physical Chemistry).

Stabrovskyi A.I. Electrolytic brassplating from non-cyanide solutions // J. Gen. Chem. USSR. 1951. V. 21. P. 1333-1339. This is a part of 1947 PhD thesis of Andrei Ivanovich Stabrovskyi, who later worked for atomic project, dealing with electrochemistry of uranium. etc, and also with electrolytic processing of reactor materials.

Mikhailov V.V. The action of additives on metals electrodeposition // Uspekhi Khimii. 1951. V. 20. P. 194-212, in Russian. Review with 77 Refs.

Pazukhin V.A. Crystal chemistry knowledge as applied to fabrication of aluminum by electrolysis // Uspekhi Khimii. 1952. V. 21. P. 313-336, in Russian. Vasilyi Aleksandrovich Pazukhin (1889-1972) was metallurgical engineer educated in Tomsk, who moved to Moscow in the beginning of 1920s, and worked in the Institute of Non-Ferrous metals and Gold in 1934 – 1954. Objections to some statements of this article were published by Georgyi Alekseyevich Abramov from the Leningrad Polytechnical Institute (Uspekhi Khimii. 1953. V.22. P. 99-105, in Russian).

Shluger M.A. The setup for the studies of internal strain in electrolytic deposits // Zavodskaya Laboratoriya. 1953. V. 19. P. 1097-1098, in Russian. Mikhail Aleksandrovich Shluger (1924-1997) was affiliated with Moscow Night Metallurgical Institute (technical University for education of people working during the day).

Izgaryshev N.A., Fioshin M.Ya. On the role of the state of the surface of the cathode in the electroreduction of aromatic nitro compounds // J. Gen. Chem. USSR. 1954. V. 24. P. 773-779.

Izgaryshev N.A., Fioshin M.Ya. The progress of electrosynthesis in organic chemistry // Uspekhi Khimii. 1956. V. 25. P. 486-516, in Russian. Review with 179 Refs.

Skanavi-Grigorieva M.S., Staroverova V.I. Investigation of anode deposits formed in the electrolysis of solutions of certain thallium salta. III // J. Gen. Chem. USSR. 1958. V. 28. P. 1737-1740. Mariya Semenovna Skanavi-Grigorieva (1881-1958) was educated in StPetersburg, Leipzig, and Zurich (PhD in Werner’s lab). When back to Russia, she was mostly dealing with coordination chemistry of rare and noble metals, and worked at various cities, including (from ca. 1939) Moscow Pedagogical Institute (МГПИ) indicated in this article.

Fioshin M.Ia., Kazakova L.I. Synthesis of lead tetraacetate by electrochemical oxidation of lead diacetate at the anode // J. Gen. Chem. USSR. 1958. V. 28. P. 2043-2045.

Zelenova V.D. Electrolytic separation of martensite and austenite from hardened steel // Industrial Laboratory. 1958. V. 24. P. 58-60. This article is affiliated with Automobile and Motorcar <Motor Engine> Institute (НАМИ).

Kliachko Iu.A., Shapiro M.M., Mal’tseva V.S., Mil’chev V.A. Investigation relating to the theory of electrochemical phase analysis of alloys // Industrial Laboratory. 1958. V. 24. P. 1441-1446. Institute of Ferrous Metallurgy (ЦНИИчермет), Moscow. Yuriy Abramovich Klyachko (1910-2004) is know as a broad range analytical chemist, who worked in this institute in 1944-1963. During various periods, he also headed analytical chemistry departments in several technical universities and military academies.

Gerasimov V.V., Gromova A.I., Sabinin A.A. The autoclave for electrochemical studies at high temperatures and pressures // Industrial Laboratory. 1958. V. 24. P. 1548-1549. The presented autoclave could be used for polarization measuremets up to 350oC and 200 atm. Valentin Vladimirovich Gerasimov (1925-2001) was an expert in corrosion of materials for nuclear power plants, etc. He graduated from Moscow Steel Institute (1951), completed his PhD thesis in the Institute of Physical Chemistry (1956), and then was assigned to work as a head of corrosion lab in a secret institution formally named “Institute of power engineering”.

Efimov E.A., Erusalimchik I.G. Anodic dissolution of silicon in hydrofluoric acid // Rus. J. Phys. Chem. 1961. V. 35. P. 185-187.

Efimov E.A., Erusalimchik I.G. Anodic dissolution of germanium in the presence of reducing agents // Rus. J. Phys. Chem. 1961. V. 35. P. 266-268.

Efimov E.A., Erusalimchik I.G. Surface state of anodically polarized germanium in acid solutions // Rus. J. Phys. Chem. 1962. V. 36. P. 49-52.

Efimov E.A., Erusalimchik I.G., Sokolova G.P. Oxidation of the germanium surface in chemical etching // Rus. J. Phys. Chem. 1962. V. 36. P. 398-400.

Efimov E.A., Erusalimchik I.G., Sokolova G.P. Electrochemical hydrogen evolution at a single crystal of silicon in dilute hydrofluoric acid // Rus. J. Phys. Chem. 1962. V. 36. P. 524-527.

Efimov E.A., Erusalimchik I.G., Sokolova G.P. Surface state of anodically polarized silicon in dilute hydrofluoric acid // Rus. J. Phys. Chem. 1962. V. 36. P. 645-646.

Andreyev L.A. Improved method for measurement of contact difference of potentials with a vibrating wire // Industrial Laboratory. 1962. V. 28. P. 1018-1021. Russian version: Zavodskaya Laboratoriya. 1962. V. 28. P. 962-965. Moscow Steel Institute.

Tumanov V.I., Trukhanova Z.S., Funke V.F., Shcherbakova V.G. The electrochemical separation and investigation of the contacting and carbide phases of hard tungsten-cobalt alloys // Industrial Laboratory. 1963. V. 29. P. 272-275. Russian version: Zavodskaya Laboratoriya. 1963. V. 29. P. 277-280. Affiliated with the Institute of Hard Alloys.

Efimov E.A., Erusalimchik I.G., Gorgoraki E.I. Reduction of the peroxodisulfate ion at a germanium cathode // Rus. J. Phys. Chem. 1964. V. 38. P. 379-381.

Efimov E.A., Erusalimchik I.G. Reduction of organic compounds at a germanium cathode // Rus. J. Phys. Chem. 1964. V. 38. P. 1560-1564.

Klyachko Yu.F., Baranova G.K. The electrochemical phase analysis of high-carbon steels // Industrial Laboratory. 1964. V. 30. P. 1636-1638. Russian version: Zavodskaya Laboratoriya. 1964. V. 30. P. 1318-1321. Affiliated with the Institute of Ferrous Metallurgy.

Kvokova I.M., Lainer V.I. Electrodeposition of thick, dense rhenium coatings // Protection of Metals. 1965. V. 1. P. 459-463. Russian version: Zashchita Metallov. 1965. V. 1. P. 515-520. Moscow Institute of Steel and Alloys.

Rezin B.L., Lainer V.I. Anodic and cathodic polarization in copper pyrophosphate electrolyte // Protection of Metals. 1966. V. 2. P. 285-288. Russian version: Zashchita Metallov. 1966. V. 2. P. 339-343. Moscow Institute of Steel and Alloys.

Nechaev E.A., Beck R.Yu., Solov’ev G.S., Kudryavtsev N.T. Influence of indifferent salts on the quality of electrolytic silver coationgs from cyanide electrolytes // Protection of Metals. 1967. V. 3. P. 440-442. Russian version: Zashchita Metallov. 1967. V. 3. P. 512-514.

Vorob’eva N.S., Kunakov Ya.N. Use of method of anodic oxidation in studying the microstructures of certain superconducting alloys // Industrial Laboratory. 1968. V. 34. P. 1806-1807. Russian version: Zavodskaya Laboratoriya. 1968. V. 34. P. 1495-1496. Institute for Rare Metals Production <Гиредмет>. Vanadium- and niobium-base binary alloys are studied.

Rybakov B.N., Sinyagovskaya L.A. Determination of corrosion-active gases in the atmosphere by the linear colorimetric method // Protection of Metals. 1969. V. 5. P. 637-639. Russian version: Zashchita Metallov. 1969. V. 5. P. 716-718.

Rybakov B.N., Maslova G.V., Zalkind D.I. Atmospheric corrosion of thallium // Protection of Metals. 1970. V. 6. P. 406-408. Russian version: Zashchita Metallov. 1970. V. 6. P. 444-447.

Kudryavtsev N.T., Nechaev E.A., Semenov V.A. Reason for the reduction of current efficiency during the electrodeposition of copper from sulfuric acid solutions // Protection of Metals. 1970. V. 6. P. 429-432. Russian version: Zashchita Metallov. 1970. V. 6. P. 469-473.

Efimov I.A., Rybakov B.N., Knyazhenko L.A., Maslova G.V., Kharitonov Yu.Ya. The use of infrared spectroscopy to investigate the corrosion products of copper // Protection of Metals. 1971. V. 7. P. 382-384. Russian version: Zashchita Metallov. 1971. V. 7. P. 439-441.

Efimov I.A., Rybakov B.N., Knyazhenko L.A., Maslova G.V., Kharitonov Yu.Ya. Composition of the atmospheric corrosion products of aluminum // Protection of Metals. 1972. V. 8. P. 524-526. Russian version: Zashchita Metallov. 1972. V. 8. P. 580-583.

Efimov I.A., Rybakov B.N., Maslova G.V., Kharitonov Yu.Ya. Phase composition and thermal stability of products from atmospheric corrosion of lead // Protection of Metals. 1972. V. 8. P. 644-645. Russian version: Zashchita Metallov. 1972. V. 8. P. 711-712. This article is affiliated with “Central scientific-research laboratory”, which most probably means an applied institution transformed into the Institute of Corrosion Protection (ВНИИК) in early 1970s.

Rybakov B.N., Moskvicheva A.F., Beregovaya G.D. Corrosion of lanthanum under atmospheric conditions // Protection of Metals. 1973. V. 9. P. 278-280. Russian version: Zashchita Metallov. 1973. V. 9. P. 303-306.

Zotova L.M., Blashchuk V.E., Maksimov Yu.A., Vavilova V.V. Corrosion of welded joints in AK-1 and AK-2 alloys under stress // Protection of Metals. 1973. V. 9. P. 628-629. Russian version: Zashchita Metallov. 1973. V. 9. P. 707-709.

Rybakov B.N., Efimov I.A. Laboratory apparatus for the study of atmospheric corrosion in a corrosive gas duct // Protection of Metals. 1974. V. 10. P. 104-105. Russian version: Zashchita Metallov. 1974. V. 10. P. 107-109.

Arons V.I., Midal L.L., Zhuk N.P., Rybakov B.N. Hydrogen embrittlement of niobium // Protection of Metals. 1974. V. 10. P. 664-665. Russian version: Zashchita Metallov. 1974. V. 10. P. 729-731. Affiliated with the Institute of rare earth metals.

Efimov E.A., Gerish T.V., Erusalimchik I.G. Chemical gold plating using sodium borohydride as reducing agent // Protection of Metals. 1975. V. 11. P. 365-366. Russian version: Zashchita Metallov. 1975. V. 11. P. 383-385.

Makarova N.G., Lainer V.I. Mechanism of the discharging of PdCl4— ions // Protection of Metals. 1975. V. 11. P. 421-424. Russian version: Zashchita Metallov. 1975. V. 11. P. 453-457.

Kaputkin I.I., Salikhadzhanova R. M.-F., Bryksin I.E. Nomograms for the selection of parameters for taking down <registration> and recording polarization curves // Protection of Metals. 1976. V. 12. P. 216-218. Russian version: Zashchita Metallov. 1976. V. 12. P. 232-234. This can sound funny today, but the issue was important for recording the curves on the paper by means of single-coordinate ink recorder <KSP-4>. The rate of paper movement had to be agreed with potential scan rate.

Efimov E.A., Gerish T.V., Erusalimchik I.G. Mechanism of chemical gold plating from borohydride electrolyte // Protection of Metals. 1976. V. 12. P. 631-633. Russian version: Zashchita Metallov. 1976. V. 12. P. 724-726.

Bushin V.G., Kudryavtsev N.T., Vagramyan T.A., Baeva A.I. Electrodeposition of zinc from zincate electrolyte at high current densities // Protection of Metals. 1978. V. 14. P. 513-515. Russian version: Zashchita Metallov. 1978. V. 14. P. 623-625.

Kovaleva O.I., Kudryavtsev N.T., Vagramyan T.A. Electrodeposition of brass from alkaline tartrate-citrate solutions // Protection of Metals. 1979. V. 15. P. 186-188. Russian version: Zashchita Metallov. 1979. V. 15. P. 226-228.

Kovaleva O.I., Kudryavtsev N.T., Vagramyan T.A. Electrodeposition of brass from alkali-tartrate electrolytes // Protection of Metals. 1980. V. 16. P. 147-149. Russian version: Zashchita Metallov. 1980. V. 16. P. 185-187.

Kovaleva O.I., Matyukhin S.A., Panova O.I., Vagramyan T.A. Electrodeposition of brasses from pyrophosphate electrolytes // Protection of Metals. 1981. V. 17. P. 480-482. Russian version: Zashchita Metallov. 1981. V. 17. P. 597-598.

Related scientific events/meetings

Conference of young corrosion scientists, 1966 (arranged by the Institite of Physical Chemistry)

Seminar on corrosion protection for workers of chemical industry, 1967 (arranged by Karpov Institute)

(c) Galina Tsirlina, unless specified otherwise

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