Vladimir Sergeevich Bagotsky

Vladimir Sergeevich Bagotsky (1920-2012), spent the early part of his life in Switzerland, entered Moscow University in 1938, and graduated in 1944. His PhD thesis on hydrogen evolution on mercury (1947) was supervised by Z.A. Iofa. In late 1940s, he started his oxygen reduction research, co-authored “Kinetics of electrode processes”, and participated in sharp discussions on atomic hydrogen, e.g. found himself in the center of the professional life at the Dept, but it was possible only until the “fight with anti-cosmopolitants” started. This campaign forced him to leave the University in 1949, and move to the All-Union Research Institute “Cells-Electrocarbon” (later known as the Institute of Power Sources, VNIIT). His successful development of silver-zinc batteries for the soviet space program made Bagotsky the real leader of power sources research in the country. In 1960s, he became the head of the state fuel cell program. Finally, it became possible to establish his division in Frumkin Institute in 1965, and many of his pupils and colleagues from VNIIT joined him in this new unit, see their names and main topics below. This memorial article contains Bagotsky’s complete list of articles and books, as well as many photos. His principle team members from both Frumkin Inst and VNIIT are presented at this page (alphabetic order).

Some early Bagotsky’s publications and translations of some articles published in Russian (under construction)

Bagotsky V.S. The dependence of hydrogen overvoltage on the mercury cathode on solution composition // Doklady Akademii Nauk SSSR. 1947. V. 58. P. 1387-1390, in Russian.

Bagotsky V.S. On the theory of concentrational polarization on the dropping mercury electrode. II. Zhurnal Fizicheskoi Khimii. 1948. V. 22. P. 1466-1475, in Russian. Part I is authored by matematician Naum Natanovich Maiman (1912-2001), Zhurnal Fizicheskoi Khimii. 1948. V. 22. P. 1454-1465, in Russian.

Bagotsky V.S., Yablokova I.E. The kinetics of hydrogen evolution on the mercury cathode from buffer solutions // Zhurnal Fizicheskoi Khimii. 1949. V. 23. P. 413-421, in Russian.

Bagotsky V.S., Motov D.L. The reversible oxygen electrode on mercury in alkaline solutions and the mechanism of cathodic oxygen reduction. Doklady Akademii Nauk SSSR. 1950. V. 71. P. 501-504, in Russian.

Bagotsky V.S., Yablokova I.E. Mechanism of electrochemical reduction of oxygen and hydrogen peroxide on mercury electrode // Zhurnal Fizicheskoi Khimii. 1953. V. 27. P. 1663-1675, in Russian.

Bagotsky V.S., Yablokova I.E. On the mechanism of catalytic decomposition of the hydrogen peroxide at the mercury surface // Doklady Akademii Nauk SSSR. 1954. V. 95. P. 1219-1221, in Russian.

Shteinberg G.V., Bagotsky V.S. Certain Features of the cathodic reduction of chromic acid at a carbon electrode // Doklady Akademii Nauk SSSR. 1957. V. 115. P. 568-571, in Rissian. Translated version: Proc. Akad. Sci. USSR Phys. Chem. Section. 1957. V. 115. P. 575-578.

Popova T.I., Bagotsky V.S., Kabanov B.N. The anodic passivation of zinc in alkaline solutions // Doklady Akademii Nauk SSSR. 1960. V. 132. P. 639-642, in Russian. Translated version: Proc. Akad. Sci. USSR Phys. Chem. Section. 1960. V. 132. P. 445-447.

Oshe A.I., Bagotsky V.S. The mechanism of the cathodic reduction of zinc oxide layers on a zinc electrode // Rus. J. Phys. Chem. 1961. V. 35. P. 806-808.

Popova T.I., Bagotsky V.S., Kabanov B.N. The anodic passivation of zinc in alkali. I. Mesurements at constant current densities // Rus. J. Phys. Chem. 1962. V. 36. P. 766-770.

Popova T.I., Bagotsky V.S., Kabanov B.N. The anodic passivation of zinc in alkali. II. Potentiostatic and alternating current mesurements; determination of charging curves // Rus. J. Phys. Chem. 1962. V. 36. P. 770-773.

Vasil’ev Yu.B., Bagotsky V.S. Electrochemical oxidation of formic acid and its salts on a rotating platinum electrode // Doklady Physical Chemistry. 1963. V. 148. P. 7-9. Russian version: Doklady Akademii Nauk SSSR. 1963. V. 148. P. 132-135.

Popova T.I., Bagotsky V.S., Kabanov B.N. The effect of small quantities of metallic impurities on the value of hydrogen overpotential on zinc in concentrated alkaline solutions // Russ. J. Appl. Chem. 1963. V. 36. P. 1687-1690.

Luk’yanycheva V.I., Bagotsky V.S. The adsorption of oxygen on degassed smooth platinum in electrolyte solutions // Doklady Physical Chemistry. 1964. V. 155. P. 221-224. Russian version: Doklady Akademii Nauk SSSR. 1964. V. 155. P. 160-163.

Tikhomirova V.I., Oshe A.I., Bagotsky V.S., Luk’yanycheva V.I. The state of oxygen adsorbed on platinum // Doklady Physical Chemistry. 1964. V. 159. P. 1055-1058. Russian version: Doklady Akademii Nauk SSSR. 1964. V. 159. P. 644-647.

Matusevich L.A., Bagotsky V.S. Study of equilibrium carbonate-bicarbonate electrolyte in presence of potassium formate // J. Appl. Chem. USSR. 1966. V. 39. P. 1371-1374. Russian version: Zhurnal Prikladnoi Khimii. 1966. V. 39. P. 1463-1467.

Mandzhgaladze S.N., Mikaberidze M.P., Pirtskhalava D.N., Vassiliev Yu.B., Bagotsky V.S. Effect of chloride ions on the corrosion and electrochemical behavior of titanium in neutral solutions // Protection of Metals. 1976. V. 12. P. 154-156. Russian version: Zashchita Metallov. 1976. V. 12. P. 169-172.

Vol’fkovich Yu.M., Sosenkin V.E., Shkol’nikov E.I., Bagotsky V.S. Standardized contact porosimetry // Doklady Physical Chemistry. 1977. V. 232. P. 91-94. Russian version: Doklady Akademii Nauk SSSR. 1977. V. 232. P. 603-606.

Bagotsky V.S., Tarasevich M.R., Levina O.A., Radyushkina K.A., Andruseva S.I. Electrocatalysis of oxygen reduction at metal chelates in acidic electrolytes // Doklady Physical Chemistry. 1977. V. 233. P. 386-388. Russian version: Doklady Akademii Nauk SSSR. 1977. V. 233. P. 889-891.

Bagotsky V.S., Vol’fkovich Yu.M. Lyophobized catalyst for gas-liquid-phase reactions // Doklady Chemical Technology. 1977. V. 234. P. 93-95. Russian version: Doklady Akademii Nauk SSSR. 1977. V. 234. P. 403-406.

Luk’yanycheva V.I., Yuzhanina A.V., Tarasevich M.R., Shumilova N.A., Bagotsky V.S. Molecular oxygen reduction kinetics at preoxidized platinum electrodes in alkaline solutions // Sov. Electrochem. 1977. V. 13. P. 432-437. Russian version: Elektrokhimiya. 1977. V. 13. P. 506-511.

Bagotsky V.S., Vol’fkovich Yu.M., Golin Yu.L., Suvorov A.N., Sherstobitov Yu.S. Possible ways of producing hydrogen and oxygen from water for the purposes of a hydrogen economy // Sov. Electrochem. 1977. V. 13. P. 1389-1393. Russian version: Elektrokhimiya. 1977. V. 13. P. 1611-1616.

(c) Galina Tsirlina, unless specified otherwise

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